Mohd Maidin Siti Marina, Abdul Rahim Aisyah Saad, Abdul Hamid Shafida, Kia Reza, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 16;64(Pt 8):o1501-2. doi: 10.1107/S1600536808021314.
In the title compound, C(12)H(16)N(2)O(4), intra-molecular N-H⋯O and C-H⋯O hydrogen bonds generate S(6) and S(5) ring motifs, respectively. The nitro group is almost coplanar with the benzene ring, forming a dihedral angle of 6.2 (2)°. In the crystal structure, neighbouring mol-ecules are linked together by inter-molecular N-H⋯O and O⋯O inter-actions. Of interest are the short inter-molecular O⋯O inter-actions which cause a stacking arrangement of the mol-ecules along the a axis.
在标题化合物C₁₂H₁₆N₂O₄中,分子内的N—H⋯O和C—H⋯O氢键分别产生S(6)和S(5)环模式。硝基与苯环几乎共面,形成的二面角为6.2 (2)°。在晶体结构中,相邻分子通过分子间的N—H⋯O和O⋯O相互作用连接在一起。值得注意的是,短的分子间O⋯O相互作用导致分子沿a轴堆积排列。