4-乙基氨基-3-硝基苯甲酸
4-Ethyl-amino-3-nitro-benzoic acid.
作者信息
Narendra Babu Shivanagere Nagojappa, Abdul Rahim Aisyah Saad, Abd Hamid Shafida, Quah Ching Kheng, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):o1079. doi: 10.1107/S1600536809014196.
In the title compound, C(9)H(10)N(2)O(4), an intra-molecular N-H⋯O hydrogen-bond inter-action generates an S(6) ring motif. The nitro group is slightly twisted away from its attached benzene ring [dihedral angle = 15.29 (15)°]. In the crystal structure, mol-ecules are stacked down the a axis caused by short O⋯O(-1-x, -y, 2-z) contacts of 2.6481 (16) Å involving the O atoms of the nitro groups. The crystal packing is consolidated by inter-molecular O-H⋯O hydrogen bonds, linking the mol-ecules into centrosymmetric dimers.
在标题化合物C₉H₁₀N₂O₄中，分子内N-H⋯O氢键相互作用产生一个S(6)环 motif。硝基与相连的苯环稍有扭曲[二面角 = 15.29 (15)°]。在晶体结构中，分子沿a轴堆积，这是由涉及硝基O原子的2.6481 (16) Å的短O⋯O(-1-x, -y, 2-z)接触引起的。晶体堆积通过分子间O-H⋯O氢键得以巩固，将分子连接成中心对称的二聚体。
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