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2-氰基苯胺硝酸盐

2-Cyano-anilinium nitrate.

作者信息

Cui Li-Jing, Wen Xiao-Chun

机构信息

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 31;64(Pt 8):o1620. doi: 10.1107/S1600536808023313.

DOI:10.1107/S1600536808023313
PMID:21203310
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2962190/
Abstract

In the title compound, C(7)H(7)N(2) (+)·NO(3) (-), all atoms of the cation, with the exception of two H atoms of the NH(3) group, lie on a mirror plane, while the anion lies across this plane with the N and one O atom on the mirror plane. In the crystal structure, the organic cations and NO(3) (-) anions are linked by N-H⋯N and N-H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100).

摘要

在标题化合物C₇H₇N₂⁺·NO₃⁻中,阳离子的所有原子(除NH₃基团的两个H原子外)位于一个镜面平面上,而阴离子横跨该平面,其中N和一个O原子位于镜面上。在晶体结构中,有机阳离子和NO₃⁻阴离子通过N—H⋯N和N—H⋯O氢键相连,形成一个平行于(100)的二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd11/2962190/de4da8825f66/e-64-o1620-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd11/2962190/6b7eb30de5fd/e-64-o1620-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd11/2962190/de4da8825f66/e-64-o1620-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd11/2962190/6b7eb30de5fd/e-64-o1620-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd11/2962190/de4da8825f66/e-64-o1620-fig2.jpg

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4-Cyano-1-methyl-pyridinium nitrate.4-氰基-1-甲基吡啶硝酸盐
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