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3-O-α-D-甘露吡喃糖基-β-D-葡萄糖吡喃糖苷四水合物甲酯

Methyl 3-O-α-d-mannopyranosyl β-d-glucopyran-oside tetra-hydrate.

作者信息

Eriksson Lars, Widmalm Göran

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 31;64(Pt 8):o1639-40. doi: 10.1107/S1600536808021454.

Abstract

The title compound, C(13)H(24)O(11)·4H(2)O, forms extended hydrogen-bonded networks. These are present between disaccharides, but not as inter-residue hydrogen bonds, as well as to water mol-ecules that in addition form an inter-molecular chain of hydrogen bonds. The conformation of the disaccharide is described by the glycosidic torsion angles ϕ(H) = -34° and ψ(H) = -5°. Macroscopically, the disaccharide was observed to be hygroscopic.

摘要

标题化合物C(13)H(24)O(11)·4H(2)O形成了扩展的氢键网络。这些网络存在于二糖之间,但不是作为残基间氢键,并且还与水分子形成分子间氢键链。二糖的构象由糖苷扭转角ϕ(H)= -34°和ψ(H)= -5°描述。宏观上,观察到二糖具有吸湿性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ef8/2962246/150e8b51b2b8/e-64-o1639-fig1.jpg

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