Department of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, Pennsylvania 15260, United States.
J Am Chem Soc. 2011 Feb 9;133(5):1220-3. doi: 10.1021/ja109103t. Epub 2011 Jan 4.
Luminescent metal-organic frameworks (MOFs), Ln(3+)@bio-MOF-1, were synthesized via postsynthetic cation exchange of bio-MOF-1 with Tb(3+), Sm(3+), Eu(3+), or Yb(3+), and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution.
发光金属有机骨架（MOFs），Ln(3+)@bio-MOF-1，是通过生物 MOF-1 与 Tb(3+)、Sm(3+)、Eu(3+)或 Yb(3+)的后合成阳离子交换合成的，并研究了它们的光物理性质。我们证明了生物 MOF-1 在水溶液中封装和敏化可见和近红外发射镧系阳离子。
