一种由二钒取代的磷钨酸盐引发的高效基于 H2O2 的烯烃、炔烃和芳烃的氧化溴化反应。
An efficient H2O2-based oxidative bromination of alkenes, alkynes, and aromatics by a divanadium-substituted phosphotungstate.
机构信息
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
出版信息
Chem Commun (Camb). 2011 Feb 14;47(6):1692-4. doi: 10.1039/c0cc04889e. Epub 2011 Jan 5.
PMID:21210029
Abstract
A divanadium-substituted phosphotungstate TBA(4)[γ-HPV(2)W(10)O(40)] (TBA = tetra-n-butylammonium) could act as an effective homogeneous catalyst for the H(2)O(2)-based oxidative bromination.
摘要
一种含二钒取代的磷钨酸盐 TBA(4)[γ-HPV(2)W(10)O(40)]（TBA = 四丁基铵）可用作基于 H(2)O(2)的溴化氧化反应的高效均相催化剂。
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