一锅法合成环芳烷型大环化合物的锰(III)介导的氧化自由基环化反应。
One-pot synthesis of cyclophane-type macrocycles using manganese(III)-mediated oxidative radical cyclization.
机构信息
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan.
出版信息
Org Biomol Chem. 2011 Mar 7;9(5):1491-507. doi: 10.1039/c0ob00683a. Epub 2011 Jan 5.
PMID:21210037
Abstract
Cyclophane-type macrocyclic compounds from 21 to 56 members having two fused dihydrofuran rings were synthesized by the manganese(III)-mediated oxidation of terminal dienes with bis(3-oxobutanoate)s containing aromatics. The reaction detail, characterization and reaction pathways are described.
摘要
通过锰(III)介导的含芳烃的双(3-氧代丁二酸酯)对末端二烯的氧化，合成了具有两个稠合二氢呋喃环的 21 至 56 元环的环芳烷型大环化合物。描述了反应细节、表征和反应途径。
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