International Joint Research Center for Persistent Toxic Substances, Zhejiang University of Technology, Hangzhou 310032, China.
Chemosphere. 2011 Mar;83(2):137-43. doi: 10.1016/j.chemosphere.2010.12.070. Epub 2011 Jan 8.
The spatial distribution and source of polychlorinated biphenyls (PCBs) in 30 surface sediments of Yueqing Bay, Xiangshan Bay, and Sanmen Bay in Eastern China were analysed. Total concentrations of PCBs ranged from 9.33 to 19.60 ng g(-1) dry weight for all the sampling stations. The observed PCB levels were lower than those in areas of high urbanisation or contamination in the bay. Low-chlorinated PCBs, dominated by tri-PCB, were identified as the prevalent contaminate of surface sediments, and the top three PCB congeners were lighter chlorinated congeners (PCB 8, PCB 18 and PCB 28). These results were in agreement with the fact that tri-PCB compounds are the dominant contaminants in China. The result of the principal component analysis revealed that all samples were similar in composition to Aroclor 1242, suggesting they might originate from electrical capacitors and transformers. The levels of PCBs were significantly correlated with the total organic carbon in the sediments.
对中国东部乐清湾、象山港和三门湾 30 个表层沉积物中多氯联苯(PCBs)的空间分布和来源进行了分析。所有采样点的 PCBs 总浓度范围为 9.33-19.60ng g(-1)干重。观察到的 PCB 水平低于海湾内城市化程度高或污染严重的地区。低氯代 PCBs 以三 PCB 为主,是表层沉积物中普遍存在的污染物,前三种 PCB 同系物是低氯代同系物(PCB8、PCB18 和 PCB28)。这些结果与三 PCB 化合物是中国主要污染物的事实一致。主成分分析的结果表明,所有样品的组成与 Aroclor 1242 相似,表明它们可能来自电容器和变压器。PCBs 的水平与沉积物中的总有机碳显著相关。