基于 BODIPY 的荧光化学计量比型 Cu(II) 探针，其传感机制基于氧化脱氢反应。
A BODIPY-based fluorescent chemodosimeter for Cu(II) driven by an oxidative dehydrogenation mechanism.
机构信息
Research Center for Solar Energy Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Japan.
出版信息
Chem Commun (Camb). 2011 Mar 7;47(9):2673-5. doi: 10.1039/c0cc04069j. Epub 2011 Jan 13.
PMID:21234464
Abstract
A boradiazaindacene (BODIPY) derivative containing a simple NO bidentate ligand shows a Cu(2+)-selective fluorescence in aqueous media. This is promoted via a coordination of Cu(2+) followed by oxidative dehydrogenation of an amine moiety, leading to a formation of a fluorescent Cu(+)-Schiff base complex.
摘要
一种含有简单 NO 双齿配体的苯并二吡咯（BODIPY）衍生物在水相介质中表现出对 Cu(2+)的选择性荧光。这是通过 Cu(2+)的配位以及胺部分的氧化脱氢来促进的，导致形成荧光 Cu(+)-席夫碱配合物。
相似文献
1
A BODIPY-based fluorescent chemodosimeter for Cu(II) driven by an oxidative dehydrogenation mechanism.基于 BODIPY 的荧光化学计量比型 Cu(II) 探针，其传感机制基于氧化脱氢反应。
Chem Commun (Camb). 2011 Mar 7;47(9):2673-5. doi: 10.1039/c0cc04069j. Epub 2011 Jan 13.
2
Development of an oxidative dehydrogenation-based fluorescent probe for Cu2+ and its biological imaging in living cells.基于氧化脱氢反应的 Cu2+ 荧光探针的研制及其在活细胞中的生物成像。
Anal Chim Acta. 2012 Jul 20;735:107-13. doi: 10.1016/j.aca.2012.05.027. Epub 2012 May 26.
3
New BODIPY derivatives as OFF-ON fluorescent chemosensor and fluorescent chemodosimeter for Cu2+: cooperative selectivity enhancement toward Cu2+.新型BODIPY衍生物作为用于Cu2+的关-开型荧光化学传感器和荧光化学计量器：对Cu2+的协同选择性增强
J Org Chem. 2006 Mar 31;71(7):2881-4. doi: 10.1021/jo052542a.
4
An iminocoumarin-Cu(II) ensemble-based chemodosimeter toward thiols.基于亚胺-香豆素-Cu(II)配合物的硫醇化学传感器。
Chem Commun (Camb). 2011 May 14;47(18):5142-4. doi: 10.1039/c1cc10672d. Epub 2011 Mar 15.
5
Highly sensitive and selective "turn-on" fluorescent chemodosimeter for Cu2+ in water via Cu2+-promoted hydrolysis of lactone moiety in coumarin.基于香豆素内酯部分在 Cu2+ 作用下发生水解反应的比率型荧光“开-关”型荧光化学传感器用于水中 Cu2+ 的高灵敏和高选择性检测。
Chem Commun (Camb). 2010 May 21;46(19):3363-5. doi: 10.1039/c001408g. Epub 2010 Mar 24.
6
Specific Cu(2+)-induced J-aggregation and Hg(2+)-induced fluorescence enhancement based on BODIPY.基于 BODIPY 的特定 Cu(2+)-诱导 J-聚集和 Hg(2+)-诱导荧光增强。
Chem Commun (Camb). 2010 May 28;46(20):3565-7. doi: 10.1039/b926300d. Epub 2010 Apr 15.
7
Ratiometric and selective fluorescent chemodosimeter for Cu(II) by Cu(II)-induced oxidation.通过铜（II）诱导氧化实现的用于铜（II）的比率型选择性荧光化学传感器
Luminescence. 2008 Jan-Feb;23(1):28-31. doi: 10.1002/bio.1012.
8
Visible-near-infrared and fluorescent copper sensors based on julolidine conjugates: selective detection and fluorescence imaging in living cells.基于[化] 桥连[化] 芴化合物的可见近红外和荧光铜传感器：活细胞中的选择性检测和荧光成像。
Chemistry. 2011 Sep 26;17(40):11152-61. doi: 10.1002/chem.201101906. Epub 2011 Sep 1.
9
A BODIPY aldoxime-based chemodosimeter for highly selective and rapid detection of hypochlorous acid.基于 BODIPY 醛肟的化学探针，用于高选择性和快速检测次氯酸。
Chem Commun (Camb). 2013 Sep 14;49(71):7836-8. doi: 10.1039/c3cc44463e.
10
Fluorescent nanoparticles as selective Cu(II) sensors.作为选择性铜（II）传感器的荧光纳米颗粒。
Photochem Photobiol Sci. 2006 Mar;5(3):300-10. doi: 10.1039/b513215k. Epub 2005 Dec 20.
Zotero 插件