基于 BODIPY 的荧光化学计量比型 Cu(II) 探针，其传感机制基于氧化脱氢反应。
A BODIPY-based fluorescent chemodosimeter for Cu(II) driven by an oxidative dehydrogenation mechanism.
机构信息
Research Center for Solar Energy Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Japan.
出版信息
Chem Commun (Camb). 2011 Mar 7;47(9):2673-5. doi: 10.1039/c0cc04069j. Epub 2011 Jan 13.
PMID:21234464
Abstract
A boradiazaindacene (BODIPY) derivative containing a simple NO bidentate ligand shows a Cu(2+)-selective fluorescence in aqueous media. This is promoted via a coordination of Cu(2+) followed by oxidative dehydrogenation of an amine moiety, leading to a formation of a fluorescent Cu(+)-Schiff base complex.
摘要
一种含有简单 NO 双齿配体的苯并二吡咯（BODIPY）衍生物在水相介质中表现出对 Cu(2+)的选择性荧光。这是通过 Cu(2+)的配位以及胺部分的氧化脱氢来促进的，导致形成荧光 Cu(+)-席夫碱配合物。
Zotero 插件