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在二维液体泡沫的三个简单实验中,预计会出现快速的高原边界尺寸变化。

Rapid Plateau border size variations expected in three simple experiments on 2D liquid foams.

作者信息

Gay C, Rognon P, Reinelt D, Molino F

机构信息

Matière et Systèmes Complexes, Université Paris Diderot-Paris 7, F-75205 Paris Cedex 13, France.

出版信息

Eur Phys J E Soft Matter. 2011 Jan;34(1):2. doi: 10.1140/epje/i2011-11002-3. Epub 2011 Jan 10.

DOI:10.1140/epje/i2011-11002-3
PMID:21253804
Abstract

Up to a global scaling, the geometry of foams squeezed between two solid plates (2D GG foams) essentially depends on two independent parameters: the liquid volume fraction and the degree of squeezing (bubble thickness to diameter ratio). We describe it in two main asymptotic regimes: fully dry floor tiles, where the Plateau border radius is smaller than the distance between the solid plates, and dry pancakes, where it is larger. We predict a rapid variation of the Plateau border radius in one part of the pancake regime, namely when the Plateau border radius is larger than the inter-plate distance but smaller than the geometric mean of that distance and the bubble perimeter. This rapid variation is not related to any topological change in the foam: in all the regimes we consider, the bubbles remain in mutual lateral contact through films located at mid-height between both plates. We provide asymptotic predictions in different types of experiments on such 2D GG foams: when foam is being progressively dried or wetted, when it is being squeezed further or stretched, when it coarsens through film breakage or through inter-bubble gas diffusion. Our analysis is restricted to configurations close to equilibrium, as we do not include stresses resulting from bulk viscous flow or from non-homogeneous surfactant concentrations. We also assume that the inter-plate distance is sufficiently small for gravity to be negligible. The present work does not provide a method for measuring small Plateau border radii experimentally, but it indicates that large (and easily observable) Plateau borders should appear or disappear rather suddenly in some types of experiments with small inter-plate gaps. It also gives expected orders of magnitude that should be helpful for designing experiments on 2D GG foams.

摘要

在全局尺度上,夹在两个固体平板之间的泡沫(二维GG泡沫)的几何结构主要取决于两个独立参数:液体体积分数和挤压程度(气泡厚度与直径之比)。我们在两种主要的渐近状态下对其进行描述:完全干燥的地砖状,其中普拉托边界半径小于固体平板之间的距离;干燥的薄饼状,其中普拉托边界半径大于该距离。我们预测在薄饼状状态的一部分中,普拉托边界半径会快速变化,即当普拉托边界半径大于板间距离但小于该距离与气泡周长的几何平均值时。这种快速变化与泡沫中的任何拓扑变化无关:在我们考虑的所有状态下,气泡通过位于两板中间高度的薄膜保持相互横向接触。我们针对此类二维GG泡沫在不同类型的实验中提供渐近预测:当泡沫逐渐干燥或湿润时,当它被进一步挤压或拉伸时,当它通过膜破裂或气泡间气体扩散而粗化时。我们的分析仅限于接近平衡的构型,因为我们没有考虑由体粘性流或非均匀表面活性剂浓度产生的应力。我们还假设板间距离足够小,以至于重力可以忽略不计。本工作没有提供一种通过实验测量小普拉托边界半径的方法,但它表明在一些板间间隙小的实验类型中,大的(且易于观察到的)普拉托边界应该会突然出现或消失。它还给出了预期的数量级,这应该有助于设计关于二维GG泡沫的实验。

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本文引用的文献

1
The transition from two-dimensional to three-dimensional foam structures.从二维泡沫结构到三维泡沫结构的转变。
Eur Phys J E Soft Matter. 2002 Apr;7(4):311-5. doi: 10.1140/epje/i2001-10099-1.
2
Osmotic pressure and structures of monodisperse ordered foam.单分散有序泡沫的渗透压与结构
Langmuir. 2008 Jan 15;24(2):418-25. doi: 10.1021/la702309h. Epub 2007 Dec 8.
Eur Phys J E Soft Matter. 2019 Jan 21;42(1):6. doi: 10.1140/epje/i2019-11767-1.