双官能化丙二烯的环异构化反应：水相中 3(2H)-呋喃酮的合成。
Cycloisomerization of bifunctionalized allenes: synthesis of 3(2H)-furanones in water.
机构信息
Organic Chemistry, Dortmund University of Technology, Otto-Hahn-Strasse 6, D-44227 Dortmund, Germany.
出版信息
J Org Chem. 2011 Mar 18;76(6):1934-6. doi: 10.1021/jo102416e. Epub 2011 Feb 3.
PMID:21291172
Abstract
A simple protocol for the efficient synthesis of 3(2H)-furanones by cycloisomerization of allenic hydroxyketones is described. This transformation is achieved in water and in the absence of any expensive metal catalysts.
摘要
本文描述了一种通过烯丙基羟酮的环异构化高效合成 3(2H)-呋喃酮的简单方法。该转化在水中进行，无需任何昂贵的金属催化剂。
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