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所有离子液体都需要有机阳离子吗？[AlCl2·nAmide]+ AlCl4(-)的特性研究及与基于咪唑鎓的体系的比较。

Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4(-) and comparison with imidazolium based systems.

机构信息

Chemistry Department, University of Leicester, Leicester, LE1 7RH, UK.

出版信息

Chem Commun (Camb). 2011 Mar 28;47(12):3523-5. doi: 10.1039/c0cc04989a. Epub 2011 Feb 8.

DOI:10.1039/c0cc04989a
PMID:21301722
Abstract

The addition of a simple amide to AlCl(3) causes the formation of a liquid of the form AlCl(2)·nAmide AlCl(4)(-). The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. This ionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids.

摘要

向三氯化铝中添加一种简单的酰胺会形成一种形式为AlCl(2)·nAmide AlCl(4)(-)的液体。由此产生的材料在很宽的温度范围内都是液体，对水相对不敏感，并且具有离子液体的性质。这种离子液体被证明是一种适合用于乙酰化二茂铁和铝电沉积的介质，并证明并非总是需要季铵阳离子才能形成离子液体。

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