Ionic liquids as electrolytes in aluminum electrolysis.

Herein, the characteristics, research progress, and application prospects of ionic liquid-based electrolytic aluminum deposition are reviewed and analyzed in comparison with the Hall-Héroult method. The reaction conditions and production procedures of this material are discussed alongside the problems ionic liquids face in the electrolytic aluminum industry. Ionic liquid-based electrolytic aluminum deposition realizes the electrolytic aluminum reaction at low temperatures, achieving a reaction energy consumption close to the theoretical minimum value. The reaction also avoids harmful CO or HF emissions, demonstrating a green and environmental-friendly approach to the production of electrolytic aluminum. In the future, in-depth work on the implementation of ionic liquid electrolytes should be carried out, establishing the necessary technical criteria and laying the foundation for the integration of this approach.