Department of Chemistry, University of Liverpool, Crown Str., Liverpool L69 7ZD, UK.
Chem Commun (Camb). 2011 Mar 28;47(12):3389-91. doi: 10.1039/c0cc05559j. Epub 2011 Feb 17.
The coordination of adenine to Ni(2+) forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO(2) over CH(4) and an isosteric heat which increases with guest loading.
腺嘌呤与 Ni(2+)的配位作用形成二聚单元，这些二聚单元可通过 3,5-吡唑二甲酸连接成链，在水热条件下通过氢键进一步组装成一个稳定的多孔网络。该材料对 CO(2)具有选择性，对 CH(4)的选择性较低，且等温热随着客体负载的增加而增加。
