新型具有杂金属[Fe-Ag]构筑单元的三维金属有机骨架：合成、晶体结构和功能研究。
New three-dimensional metal-organic framework with heterometallic [Fe-Ag] building units: synthesis, crystal structure, and functional studies.
机构信息
Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany.
出版信息
Inorg Chem. 2011 Apr 4;50(7):2714-6. doi: 10.1021/ic1019636. Epub 2011 Mar 1.
PMID:21361297
Abstract
A new three-dimensional metal-organic framework (MOF) containing Fe(II) and Ag(I) ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.
摘要
一种新型的含有 Fe(II) 和 Ag(I) 离子以及 2-吡嗪羧酸（pcaH）的三维金属有机骨架（MOF）被合成出来，并研究了其磁性和催化性能。该 MOF 具有 12.1×12.0Å 的大窗口尺寸，溶剂可及空间为 23.8%，对路易斯酸催化具有尺寸选择性。
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