Maniam Palanikumar, Stock Norbert
Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Kiel, Germany.
Acta Crystallogr C. 2011 Mar;67(Pt 3):m73-6. doi: 10.1107/S0108270111005105. Epub 2011 Feb 16.
The hydrothermal reaction of SnCl(2)·2H(2)O with 4-phosphonobenzenesulfonic acid (H(3)L) and sodium hydroxide has yielded the title compound, poly[μ-hydroxido-μ(7)-(4-phosphonatobenzenesulfonato)-ditin(II)], Sn(2)(C(6)H(4)O(6)PS)(OH). The inorganic building unit is an Sn(4)O(12) cluster which is composed of edge-sharing SnO(4) and SnO(5) polyhedra. The clusters are interconnected via P and S atoms from the organic acid to form layers in the ab plane. These layers are linked to each other through pillaring benzene groups parallel to the c axis to form a three-dimensional structure.
二水合氯化亚锡（SnCl₂·2H₂O）与4-膦酰基苯磺酸（H₃L）及氢氧化钠发生水热反应，生成了标题化合物聚[μ-羟基-μ(7)-(4-膦酰基苯磺酸根)-二亚锡(II)]，[Sn₂(C₆H₄O₆PS)(OH)]ₙ。无机构筑单元是一个Sn₄O₁₂簇，它由共享边的SnO₄和SnO₅多面体组成。这些簇通过有机酸中的P和S原子相互连接，在ab平面上形成层状结构。这些层通过平行于c轴的支撑苯环基团相互连接，形成三维结构。
