1,1'-偶氮双(四唑): 一种具有 N10 链的高能富氮化合物。
1,1'-azobis(tetrazole): a highly energetic nitrogen-rich compound with a N10 chain.
机构信息
Department of Chemistry, Energetic Materials Research, Ludwig-Maximilians Universität München, Munich, Germany.
出版信息
Inorg Chem. 2011 Apr 4;50(7):2732-4. doi: 10.1021/ic200071q. Epub 2011 Mar 8.
PMID:21384800
Abstract
The reaction of 1-aminotetrazole with acidic sodium dichloroisocyanurate allowed isolation of 1,1'-azobis(tetrazole). The rare chain of 10 nitrogen atoms in this compound was confirmed by X-ray crystallography, and the physical and explosive properties of the azo compound were characterized. The title compound possesses both exceedingly high explosive performance and sensitivity.
摘要
1-氨基四唑与酸性二氯异氰尿酸钠反应得到 1,1'-偶氮四唑。通过 X 射线晶体学证实了该化合物中罕见的 10 个氮原子链，并对该偶氮化合物的物理和爆炸性能进行了表征。该标题化合物具有极高的爆炸性能和感度。
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