Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Nanoscale. 2011 May;3(5):2074-85. doi: 10.1039/c0nr00958j. Epub 2011 Mar 8.
The nature of the mixed electronic type metallic (M-) and semiconducting (S-) single-walled carbon nanotubes (SWNTs) synthesized by current methods has posed a key challenge for the development of high performance SWNT-based electronic devices. The precise measurements of M- to S-SWNT ratio in as-grown or separated samples are of paramount importance for the controlled synthesis, separation and the realization of various applications. The objective of this review is to provide comprehensive overview of the progress achieved so far for measuring the M/S ratio both on individual and collective levels of SWNT states. We begin with a brief introduction of SWNT structures/properties and discussion of the problems and difficulties associated with precise measurement of the M/S ratio, and then introduce the principles for obtaining distinguished signals from M-and S-SWNTs. These techniques are classified into different groups based either on the single/ensemble detection of SWNT samples or on the principles of techniques themselves. We then present the M/S ratio evaluation results of these methods, with emphasis on scanning probe microscopy (SPM)-based detection techniques. Finally, the prospects of precise and large-scale measurement of M/S ratio in achieving controlled synthesis and understanding growth mechanism of SWNTs are discussed.
目前的合成方法得到的混合电子型金属(M-)和半导体(S-)单壁碳纳米管(SWNTs)的性质对高性能 SWNT 基电子器件的发展构成了关键挑战。在生长或分离的样品中精确测量 M-到 S-SWNT 的比例对于控制合成、分离和实现各种应用至关重要。本综述的目的是全面概述迄今为止在测量单个和集体 SWNT 状态的 M/S 比方面取得的进展。我们首先简要介绍 SWNT 的结构/性质,并讨论精确测量 M/S 比所涉及的问题和困难,然后介绍从 M-和 S-SWNTs 中获得区分信号的原理。这些技术根据 SWNT 样品的单个/整体检测或技术本身的原理分为不同的组。然后,我们给出了这些方法的 M/S 比评估结果,重点介绍基于扫描探针显微镜(SPM)的检测技术。最后,讨论了在实现 SWNTs 的控制合成和理解生长机制方面精确和大规模测量 M/S 比的前景。