Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Sector 67, S. A. S. Nagar, Punjab 160 062, India.
Chem Commun (Camb). 2011 Apr 21;47(15):4538-40. doi: 10.1039/c1cc10151j. Epub 2011 Mar 9.
Hydrogen bond induced reactivity and selectivity control in the 1-butyl-3-methylimidazolium based ionic liquid catalysed reaction of thiols with α,β-unsaturated carbonyl compounds is reported with remarkable influence of the anion and the C-2 hydrogen in catalytic activity and reversal of selectivity.
氢键诱导的反应性和选择性控制在 1-丁基-3-甲基咪唑鎓基离子液体催化的硫醇与α,β-不饱和羰基化合物的反应中得到了报道，阴离子和 C-2 氢对催化活性和选择性反转有显著影响。
