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离子液体功能化磁性纳米结构作为一种高效催化剂,用于合成 6H-色烯并[4,3-b]喹啉-6-酮。

Ionic liquid-functionalized magnetic nanostructures as an efficient catalyst for the synthesis of 6H-chromeno[4,3-b]quinolin-6-ones.

机构信息

School of Chemistry, College of Science, University of Tehran, P. O. Box: 14155-6455, Tehran, Iran.

Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, 14176, Iran.

出版信息

Mol Divers. 2017 Aug;21(3):597-609. doi: 10.1007/s11030-017-9746-7. Epub 2017 May 5.

Abstract

A novel imidazole ionic liquid (IL)-functionalized [Formula: see text]-[Formula: see text] ([Formula: see text]) is prepared by the functionalization of [Formula: see text] by 1-butyl-3-(3-trimethoxypropyl)-1H-imidazol-3-ium chloride as the IL moiety. The catalyst is characterized by transmission electron microscopy, scanning electron microscope, vibrating sample magnetometer, dynamic light scattering and Fourier transform infrared spectroscopy. [Formula: see text] showed good activity in the synthesis of 6H-chromeno[4,3-b]quinolin-6-one derivatives via multicomponent reaction of 4-hydroxycoumarin, anilines and benzaldehydes. The nanocatalyst is magnetically separable and easily recoverable and showed successful activity up to 10 runs.

摘要

一种新型的咪唑离子液体(IL)功能化[化学式:见正文] - [化学式:见正文]([化学式:见正文])是通过将[化学式:见正文]用 1-丁基-3-(3-三甲氧基丙基)-1H-咪唑-3-𬭩氯化物官能化得到的。该催化剂通过透射电子显微镜、扫描电子显微镜、振动样品磁强计、动态光散射和傅里叶变换红外光谱进行了表征。[化学式:见正文]在通过 4-羟基香豆素、苯胺和苯甲醛的多组分反应合成 6H-色烯并[4,3-b]喹啉-6-酮衍生物方面表现出良好的活性。纳米催化剂具有磁性可分离性和易于回收性,并在 10 次运行中表现出成功的活性。

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