Department of Materials, Polymer Physics, ETH Zürich, CH-8093 Zürich, Switzerland.
J Phys Condens Matter. 2010 Mar 17;22(10):104117. doi: 10.1088/0953-8984/22/10/104117. Epub 2010 Feb 23.
We analyze connectivity and space-filling properties of colloidal gels obtained in a model with directional interactions. We compare gels formed upon slow cooling with the ones produced via quenching. The aggregation process is qualitatively different upon quenching: the cluster size distribution shows a percolation type of behavior but not the fully connected network achieved upon slow cooling. Because quenching favors the formation of defects, differently from systems where quenching tends to produce lower local connectivity and more open structures, here it favors instead more connected, but less space-filling, structures.
我们分析了在具有定向相互作用的模型中获得的胶体凝胶的连通性和空间填充特性。我们比较了缓慢冷却形成的凝胶和淬火形成的凝胶。淬火时的聚集过程在性质上有所不同:团簇大小分布表现出渗流类型的行为,而不是缓慢冷却时形成的完全连通网络。由于淬火有利于缺陷的形成,与淬火倾向于产生较低局部连通性和更开放结构的系统不同,在这里它反而有利于更连通但空间填充度较低的结构。