在水中形成模板化动态隐色大环。
Templated dynamic cryptophane formation in water.
机构信息
Rutgers, The State University of New Jersey, Department of Chemistry and Chemical Biology, 610 Taylor Road, Piscataway, NJ 08817, USA.
出版信息
Chem Commun (Camb). 2011 Apr 21;47(15):4511-3. doi: 10.1039/c1cc10510h. Epub 2011 Mar 11.
PMID:21399790
Abstract
Several dynamic hexaimine cryptophanes, that are built up from two triformylcyclotribenzylene cavitands and three diamino linkers and spontaneously assemble in water in the presence of a suitable templating guest, are reported. X-ray structure, kinetics and thermodynamics of assembly and molecular recognition properties are discussed.
摘要
几种动态六元瓜环，由两个三蝶烯衍生的杯[3]芳烃和三个二胺连接体组成，在合适的模板客体存在下自发组装在水中。讨论了组装的 X 射线结构、动力学和热力学以及分子识别特性。
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