Department of Chemistry, University of Sheffield, Sheffield, United Kingdom S3 7HF.
Dalton Trans. 2011 Apr 28;40(16):4230-5. doi: 10.1039/c1dt10125k. Epub 2011 Mar 14.
[Mn(CO)(4){S(2)CNMe(CH(2)CO(2)H)}], 1, is shown to be a CO releasing molecule providing at least three moles CO per mole of compound. The mechanism of CO loss is dissociative and reversible and was investigated using Gaussian 09 calculations. The reversible binding of CO results in a relatively stable solution of the compound, while in the presence of a CO receptor or a ligand to prevent the rebinding of CO, the CO is lost rapidly. The X-ray structure was determined.
[Mn(CO)(4){S(2)CNMe(CH(2)CO(2)H)}], 1, 被证明是一种 CO 释放分子，每摩尔化合物至少提供 3 摩尔 CO。CO 损失的机制是离解的和可逆的，并使用 Gaussian 09 计算进行了研究。CO 的可逆结合导致化合物的相对稳定溶液，而在存在 CO 受体或防止 CO 再结合的配体的情况下，CO 迅速失去。X 射线结构已确定。
