一种高效通用的铁催化碳-碳键活化反应，以1,3-二羰基单元作为离去基团。 - Suppr

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An efficient and general iron-catalyzed C-C bond activation with 1,3-dicarbonyl units as a leaving groups.

作者信息

Li Huanrong, Li Wenjuan, Liu Weiping, He Zhiheng, Li Zhiping

机构信息

Department of Chemistry, Renmin University of China, Beijing, PR China.

出版信息

Angew Chem Int Ed Engl. 2011 Mar 21;50(13):2975-8. doi: 10.1002/anie.201006779. Epub 2011 Feb 23.

DOI:10.1002/anie.201006779

PMID:21404380

Abstract

摘要

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An efficient and general iron-catalyzed C-C bond activation with 1,3-dicarbonyl units as a leaving groups.

作者信息

Li Huanrong, Li Wenjuan, Liu Weiping, He Zhiheng, Li Zhiping

机构信息

Department of Chemistry, Renmin University of China, Beijing, PR China.

出版信息

Angew Chem Int Ed Engl. 2011 Mar 21;50(13):2975-8. doi: 10.1002/anie.201006779. Epub 2011 Feb 23.

DOI:10.1002/anie.201006779

PMID:21404380

Abstract

摘要

相似文献

An efficient and general iron-catalyzed C-C bond activation with 1,3-dicarbonyl units as a leaving groups.

Angew Chem Int Ed Engl. 2011 Mar 21;50(13):2975-8. doi: 10.1002/anie.201006779. Epub 2011 Feb 23.

Iron-promoted C-C bond cleavage of 1,3-diketones: a route to 1,2-diketones under mild reaction conditions.

J Org Chem. 2011 Jul 15;76(14):5732-7. doi: 10.1021/jo200840y. Epub 2011 Jun 16.

Highly efficient and expedient synthesis of 5-hydroxy-1H-pyrrol-2-(5H)-ones from FeCl3-catalyzed tandem intramolecular enaminic addition of tertiary enamides to ketones and 1,3-hydroxy rearrangement.

Org Lett. 2010 Sep 3;12(17):3918-21. doi: 10.1021/ol101607z.

Iron(III)-catalyzed Conia-ene cyclization of 2-alkynic 1,3-dicarbonyl compounds.

J Org Chem. 2012 Jun 15;77(12):5239-44. doi: 10.1021/jo300957q. Epub 2012 May 30.

Iron-catalyzed C-O bond activation for the synthesis of propargyl-1,2,3-triazoles and 1,1-bis-triazoles.

Org Lett. 2010 Aug 6;12(15):3308-11. doi: 10.1021/ol101082v.

Ligand-controlled iron-catalyzed coupling of α-substituted β-ketoesters with phenols.

Org Lett. 2012 Jul 6;14(13):3324-7. doi: 10.1021/ol301297k. Epub 2012 Jun 13.

Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate.

Chem Commun (Camb). 2010 Dec 14;46(46):8860-2. doi: 10.1039/c0cc03781h. Epub 2010 Oct 21.

Oxidative aromatic C-O bond formation: synthesis of 3-functionalized benzo[b]furans by FeCl3-mediated ring closure of alpha-aryl ketones.

Org Lett. 2009 Nov 5;11(21):4978-81. doi: 10.1021/ol902157c.

Iron-catalyzed ene-type propargylation of diarylethylenes with propargyl alcohols.

Org Biomol Chem. 2012 Jan 14;10(2):225-8. doi: 10.1039/c1ob06456h. Epub 2011 Oct 4.

Catalytic, asymmetric preparation of ketene dimers from acid chlorides.

Org Lett. 2003 Nov 27;5(24):4745-8. doi: 10.1021/ol0359517.

引用本文的文献

Novel Brønsted Acid Catalyzed C-C Bond Activation and α-Alkylation of Ketones.

Molecules. 2024 Sep 9;29(17):4266. doi: 10.3390/molecules29174266.

Diastereoselective construction of 4-indole substituted chromans bearing a ketal motif through a three-component Friedel-Crafts alkylation/ketalization sequence.

RSC Adv. 2018 Apr 25;8(28):15641-15651. doi: 10.1039/c8ra02481b. eCollection 2018 Apr 23.

Palladium-Catalyzed Cascade Carbonylation to α,β-Unsaturated Piperidones via Selective Cleavage of Carbon-Carbon Triple Bonds.

Angew Chem Int Ed Engl. 2021 Oct 4;60(41):22393-22400. doi: 10.1002/anie.202108120. Epub 2021 Sep 6.

Catalytic Carbocation Generation Enabled by the Mesolytic Cleavage of Alkoxyamine Radical Cations.

Angew Chem Int Ed Engl. 2016 Aug 16;55(34):9969-73. doi: 10.1002/anie.201604619. Epub 2016 Jul 12.