Prosvetova A P, Shormanov V K, Duritsyn E P, Iliushina T N
Sud Med Ekspert. 2010 Nov-Dec;53(6):31-4.
Optimal conditions for the identification and quantitative determination of tetraethyltiuram disulfide in "fresh" and putrefactive tissues of cadaverous liver are described for the purpose of TLC, HPLC, and IK-spectrophotometry following extraction of the compound of interest with ethyl acetate and its purification on a silicagel L column, 40/100 mcm. The persistence of tetraethyltiuram disulfide in the cadaverous tissues was evaluated. It was shown that the period during which tetraethyltiuram disulfide can be detected in the autopsied tissues decreases from 203 to 28 days with a rise in temperature from -15 degrees C to +36 degrees C.
描述了在尸检肝脏的“新鲜”和腐败组织中鉴定和定量测定二硫化四乙秋兰姆的最佳条件,目的是在使用乙酸乙酯萃取目标化合物并在40/100微米硅胶L柱上进行纯化后,采用薄层色谱法(TLC)、高效液相色谱法(HPLC)和红外分光光度法(IK-分光光度法)。评估了二硫化四乙秋兰姆在尸体组织中的持久性。结果表明,随着温度从-15摄氏度升至+36摄氏度,在尸检组织中可检测到二硫化四乙秋兰姆的时间从203天减少至28天。