Pergamenshchik V M, Uzunova V A
Korea University, Display & Semiconductor Physics, Jochiwon-eup, Yeongi-gun, Chungnam 339-700, South Korea.
Phys Rev E Stat Nonlin Soft Matter Phys. 2011 Feb;83(2 Pt 1):021701. doi: 10.1103/PhysRevE.83.021701. Epub 2011 Feb 22.
In spite of the analogy to the electrostatics, the three-dimensional colloidal nematostatics is substantially different in both its mathematical structure and its physical implications. The general tensorial structure of elastic multipoles derived in V. M. Pergamenshchik and V. O. Uzunova [Eur. Phys. J. E 23, 161 (2007); Phys. Rev. E 76, 011707 (2007)] allows for a classification of different types of colloids in the nematostatics. In comparison to their electrostatic counterparts, the elastic multipoles have one extra tensorial index. Based on this structure, we identify possible types of elastic dipoles. An elastic dipole is characterized by three coefficients--isotropic strength, anisotropy, and chirality--and a two-component vector along the unperturbed director. The relationship between the dipole type and symmetry groups is established and sketches of various representative types of dipolar colloids are given. Instead of a single electric dipole, in the nematostatics there are four different pure types (dipolar singlets) and eight mixed types of elastic dipoles (one quintet, one quartet, two triplets, and four doublets). It is shown that the full symmetry of the colloid-induced director field and the colloid's shape (body) symmetry determine different dipole components. For instance, a helicoidal component of the anchoring easy axes can make a chiral elastic dipole of a colloid with the quadrupolar shape symmetry. The interaction potentials for different singlet and doublet dipoles are derived and illustrated in terms of the dipolar dyads and elastic Coulomb law. We argue that multipole parameters must be found by pure numerical means, as from ansatz director distributions one can find only orders of their magnitudes.
尽管与静电学存在类比关系,但三维胶体向列静力学在数学结构和物理意义上都有很大不同。V. M. 佩尔加门施奇克和V. O. 乌祖诺娃 [《欧洲物理杂志E》23, 161 (2007); 《物理评论E》76, 011707 (2007)] 推导的弹性多极子的一般张量结构,使得在向列静力学中能够对不同类型的胶体进行分类。与它们的静电学对应物相比,弹性多极子有一个额外的张量指标。基于这种结构,我们确定了弹性偶极子的可能类型。一个弹性偶极子由三个系数——各向同性强度、各向异性和手征性——以及沿未受扰指向矢的一个双分量矢量来表征。建立了偶极子类型与对称群之间的关系,并给出了各种代表性偶极胶体类型的示意图。在向列静力学中,不是单一的电偶极子,而是有四种不同的纯类型(偶极单重态)和八种混合类型的弹性偶极子(一个五重态、一个四重态、两个三重态和四个二重态)。结果表明,胶体诱导的指向矢场的完全对称性和胶体形状(体)对称性决定了不同的偶极子分量。例如,锚定易轴的螺旋分量可以使具有四极形状对称性的胶体形成手征弹性偶极子。推导了不同单重态和二重态偶极子的相互作用势,并用偶极二元组和弹性库仑定律进行了说明。我们认为多极参数必须通过纯数值方法来确定,因为从假设的指向矢分布中只能找到它们量级的顺序。