Department of Fiber and Polymer Technology, Royal Institute of Technology, Stockholm, Sweden.
Biomacromolecules. 2011 May 9;12(5):1707-15. doi: 10.1021/bm200067f. Epub 2011 Mar 30.
This Article reports the influence of the protein network structure on the mechanical properties of foams produced from commercial wheat gluten using freeze-drying. Foams were produced from alkaline aqueous solutions at various gluten concentrations with or without glycerol, modified with bacterial cellulose nanosized fibers, or both. The results showed that 20 wt % glycerol was sufficient for plasticization, yielding foams with low modulus and high strain recovery. It was found that when fibers were mixed into the foams, a small but insignificant increase in elastic modulus was achieved, and the foam structure became more homogeneous. SEM indicated that the compatibility between the fibers and the matrix was good, with fibers acting as bridges in the cell walls. IR spectroscopy and SE-HPLC revealed a relatively low degree of aggregation, which was highest in the presence of glycerol. Confocal laser scanning microscopy revealed distinct differences in HMW-glutenin subunits and gliadin distributions for all of the different samples.
本文报道了使用冷冻干燥法从商业小麦面筋中制备泡沫时,蛋白质网络结构对泡沫力学性能的影响。使用碱性水溶液,在不同的面筋浓度下,制备了含有或不含有甘油、细菌纤维素纳米纤维改性或同时含有两者的泡沫。结果表明,20wt%的甘油足以进行增塑,得到的泡沫具有低模量和高应变恢复。发现当纤维混入泡沫中时,弹性模量略有增加,但增加幅度较小,且泡沫结构变得更加均匀。SEM 表明纤维与基体之间具有良好的相容性,纤维在细胞壁中起到桥梁的作用。IR 光谱和 SE-HPLC 表明,在存在甘油的情况下,聚集程度相对较低。共聚焦激光扫描显微镜揭示了所有不同样品中高分子量麦谷蛋白亚基和醇溶蛋白分布的明显差异。