基于鸟嘌呤的金（I）异腈配合物自组装的 G-八聚体支架用于金（I）-金（I）相互作用。

A G-octamer scaffold via self-assembly of a guanosine-based Au(I) isonitrile complex for Au(I)-Au(I) interaction.

机构信息

Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan.

出版信息

Chem Commun (Camb). 2011 Apr 28;47(16):4682-4. doi: 10.1039/c1cc10774g. Epub 2011 Mar 21.

DOI:10.1039/c1cc10774g

PMID:21423957

Abstract

A guanosine-based Au(I) isonitrile complex was demonstrated to serve as the reliable scaffold via self-assembly, wherein the quartet and octamer were formed in the absence and presence of a potassium ion, respectively, exhibiting a switchable emission based on Au(I)-Au(I) interaction.

摘要

一种基于鸟嘌呤的金（I）异腈配合物被证明是通过自组装形成的可靠支架，其中四聚体和八聚体分别在不存在和存在钾离子的情况下形成，表现出基于金（I）-金（I）相互作用的可切换发射。