LCP UMR 6264, Aix-Marseille Université, Faculté de St Jérôme, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
Chem Commun (Camb). 2011 May 14;47(18):5286-8. doi: 10.1039/c1cc10551e. Epub 2011 Mar 31.
Mesoporous silica grafted with a tertiary amine was used as a basic nanocatalyst to promote in confined medium the enantioselective cascade rearrangement of enediynes based on the phenomenon of memory of chirality; the multi-substrates recyclable catalytic reagent could easily be recovered by simple filtration, and reused without any decrease in activity even when changing the solvent.
介孔硅烷接枝叔胺作为一种基本的纳米催化剂，用于在受限介质中促进基于手性记忆现象的烯二炔的对映选择性级联重排；多底物可回收的催化试剂可以通过简单的过滤轻易回收，并在不降低活性的情况下重复使用，即使改变溶剂也如此。
