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新型吲哚基比色和“开启”型荧光传感器用于生物重要的氟离子传感。

Novel indole based colorimetric and "turn on" fluorescent sensors for biologically important fluoride anion sensing.

机构信息

Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PR China.

出版信息

J Photochem Photobiol B. 2011 May 3;103(2):140-4. doi: 10.1016/j.jphotobiol.2011.02.021. Epub 2011 Mar 15.

Abstract

A novel indole Hydrazone receptor 1 has been synthesized by one step of condensation, which can act as an efficient colorimetric and "turn on" fluorescent sensor for fluoride anions; Benesi-Hildebrand equation indicates that 1 associates with F(-) in a 1:1 stoichiometry; [TBA]OH and (1)H NMR titration experiments indicate that the deprotonation process involved upon addition of fluoride anions.

摘要

一种新型吲哚腙受体 1 通过一步缩合合成,可作为氟阴离子的高效比色和“开启”荧光传感器;本尼希-希尔德布兰德方程表明 1 与 F(-)以 1:1 的化学计量比结合;[TBA]OH 和(1)H NMR 滴定实验表明,加入氟阴离子后涉及去质子化过程。

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