Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PR China.
J Photochem Photobiol B. 2011 May 3;103(2):140-4. doi: 10.1016/j.jphotobiol.2011.02.021. Epub 2011 Mar 15.
A novel indole Hydrazone receptor 1 has been synthesized by one step of condensation, which can act as an efficient colorimetric and "turn on" fluorescent sensor for fluoride anions; Benesi-Hildebrand equation indicates that 1 associates with F(-) in a 1:1 stoichiometry; [TBA]OH and (1)H NMR titration experiments indicate that the deprotonation process involved upon addition of fluoride anions.
一种新型吲哚腙受体 1 通过一步缩合合成,可作为氟阴离子的高效比色和“开启”荧光传感器;本尼希-希尔德布兰德方程表明 1 与 F(-)以 1:1 的化学计量比结合;[TBA]OH 和(1)H NMR 滴定实验表明,加入氟阴离子后涉及去质子化过程。