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油脂作为化学中的可再生原料。

Oils and fats as renewable raw materials in chemistry.

机构信息

Universität-Oldenburg, Institut für Reine und Angewandte Chemie, Carl-von-Ossietzky-Strasse 9-11, 26129 Oldenburg, Germany.

出版信息

Angew Chem Int Ed Engl. 2011 Apr 18;50(17):3854-71. doi: 10.1002/anie.201002767. Epub 2011 Mar 29.

Abstract

Oils and fats of vegetable and animal origin have been the most important renewable feedstock of the chemical industry in the past and in the present. A tremendous geographical and feedstock shift of oleochemical production has taken place from North America and Europe to southeast Asia and from tallow to palm oil. It will be important to introduce and to cultivate more and new oil plants containing fatty acids with interesting and desired properties for chemical utilization while simultaneously increasing the agricultural biodiversity. The problem of the industrial utilization of food plant oils has become more urgent with the development of the global biodiesel production. The remarkable advances made during the last decade in organic synthesis, catalysis, and biotechnology using plant oils and the basic oleochemicals derived from them will be reported, including, for example, ω-functionalization of fatty acids containing internal double bonds, application of the olefin metathesis reaction, and de novo synthesis of fatty acids from abundantly available renewable carbon sources.

摘要

动植物油脂是过去和现在化学工业中最重要的可再生原料。油脂化学品的生产在地理位置和原料方面发生了巨大的转变,从北美和欧洲转移到了东南亚,原料也从牛脂转向了棕榈油。在引入和种植更多含有具有有趣和所需特性的脂肪酸的新型油料植物的同时,提高农业生物多样性将变得非常重要。随着全球生物柴油生产的发展,利用食用植物油的工业问题变得更加紧迫。本文将报告过去十年中在利用植物油和由此衍生的基本油脂化学品进行有机合成、催化和生物技术方面取得的显著进展,例如,含内部双键的脂肪酸的 ω-官能化、烯烃复分解反应的应用以及利用丰富的可再生碳源从头合成脂肪酸。

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