膦与烯炔和醛的三组分及非经典反应：具有α-磷叶立德的γ-内酯的形成。
Three-component and nonclassical reaction of phosphines with enynes and aldehydes: formation of γ-lactones featuring α-phosphorus ylides.
机构信息
Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan, ROC 30010.
出版信息
Org Lett. 2011 May 6;13(9):2248-51. doi: 10.1021/ol200527t. Epub 2011 Apr 7.
PMID:21473643
Abstract
Inverted carbenoid species, generated from attack of phosphines at the α(δ')-carbon of hex-2-en-4-ynedioic acid dialkyl esters, react with aldehydes to give γ-lactones possessing an α-phosphorus ylide moiety.
摘要
反烯丙型膦物种由六氢-2-烯-4-炔二酸二烷基酯的α(δ')-碳进攻膦生成，与醛反应得到具有α-磷叶立德部分的γ-内酰胺。
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