Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
J Am Chem Soc. 2011 May 4;133(17):6493-6. doi: 10.1021/ja110398p. Epub 2011 Apr 8.
Unprecedented strong phosphorescent emission in the crystalline state is observed for a variety of vaulted trans-bis(salicylaldiminato)platinum(II) complexes which are newly synthesized as a third coordination mode of well-studied bis(salicylaldiminato) complexes. This Communication describes the dynamic photophysical properties of these complexes in the liquid and crystalline states and a mechanistic rationale for the strong emission in the crystalline state.
观察到各种拱形反式双（水杨醛亚胺）铂（II）配合物在晶态下具有前所未有的强磷光发射，这些配合物是作为研究充分的双（水杨醛亚胺）配合物的第三种配位模式新合成的。本通讯描述了这些配合物在液态和晶态下的动态光物理性质，以及在晶态下强发射的机理。
