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苯胺还原氧化石墨烯及其伴随的聚合反应。

Reduction of graphene oxide by aniline with its concomitant oxidative polymerization.

机构信息

Department of Chemical & Biomolecular Engineering, National University of Singapore, Kent Ridge 119260, Singapore.

出版信息

Macromol Rapid Commun. 2011 Apr 19;32(8):684-8. doi: 10.1002/marc.201000765. Epub 2011 Mar 22.

DOI:10.1002/marc.201000765
PMID:21480428
Abstract

Graphene oxide (GO) nanosheets are readily reduced by aniline above room temperature in an aqueous acid medium, with the aniline simultaneously undergoing oxidative polymerization to produce the reduced graphene oxide-polyaniline nanofiber (RGO-PANi) composites. The resulting RGO-PANi composites and RGO (after dissolution of PANi) were characterized by XPS, XRD analysis, TGA, UV-visible absorption spectroscopy, and TEM. It was also found that the RGO-PANi composites exhibit good specific capacitance during galvanostatic charging-discharging when used as capacitor electrodes.

摘要

氧化石墨烯(GO)纳米片在室温以上的酸性水溶液中很容易被苯胺还原,同时苯胺发生氧化聚合反应生成还原氧化石墨烯-聚苯胺纳米纤维(RGO-PANi)复合材料。所得的 RGO-PANi 复合材料和 RGO(在 PANi 溶解后)通过 XPS、XRD 分析、TGA、UV-可见吸收光谱和 TEM 进行了表征。还发现,当用作电容器电极时,RGO-PANi 复合材料在恒电流充放电过程中表现出良好的比电容。

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