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通过阳极氧化直接电化学亚胺化脂肪族伯胺。

Direct electrochemical imidation of aliphatic amines via anodic oxidation.

机构信息

Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei, 230026, PR China.

出版信息

Chem Commun (Camb). 2011 May 21;47(19):5488-90. doi: 10.1039/c1cc10871a. Epub 2011 Apr 11.

DOI:10.1039/c1cc10871a
PMID:21483914
Abstract

Direct electrochemical synthesis of sulfonyl amidines from aliphatic amines and sulfonyl azides was realized with good to excellent yields. Traditional tertiary amine substrates were broadened to secondary and primary amines. The reaction intermediates were observed and a reaction mechanism was proposed and discussed.

摘要

通过直接电化学合成法，由脂肪族胺和磺酰叠氮合成磺酰脒，产率良好到优秀。传统的叔胺底物拓宽到仲胺和伯胺。观察到了反应中间体，并提出和讨论了反应机理。

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