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电子碰撞激发四氢呋喃中的电子态。

Excitation of electronic states in tetrahydrofuran by electron impact.

机构信息

ARC Centre for Antimatter-Matter Studies, School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA 5001, Australia.

出版信息

J Chem Phys. 2011 Apr 14;134(14):144302. doi: 10.1063/1.3575454.

Abstract

We report on differential and integral cross section measurements for the electron impact excitation of the three lowest lying Rydberg bands of electronic states in tetrahydrofuran. The energy range of the present experiments was 15-50 eV with the angular range of the differential cross section measurements being 15°-90°. The important effects of the long-range target dipole moment and the target dipole polarizability, on the scattering dynamics of this system, are evident from the present results. To the best of our knowledge, there are no other theoretical or experimental data against which we can compare the cross section results from this study.

摘要

我们报告了电子碰撞激发四氢呋喃中三个最低电子态里德堡带的微分和积分截面测量结果。本实验的能量范围为 15-50eV,微分截面测量的角度范围为 15°-90°。从目前的结果可以明显看出,长程靶偶极矩和靶极极化率对该系统散射动力学的重要影响。据我们所知,目前还没有其他理论或实验数据可以与本研究的截面结果进行比较。

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