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嘧啶的电子碰撞激发的微分截面。

Differential cross sections for the electron impact excitation of pyrimidine.

机构信息

School of Chemical and Physical Sciences, Flinders University, GPO Box 2100, Adelaide, SA 5001, Australia.

出版信息

J Chem Phys. 2012 Aug 21;137(7):074304. doi: 10.1063/1.4743961.

Abstract

We report on differential cross section (DCS) measurements for the electron-impact excitation of the electronic states of pyrimidine. The energy range of the present measurements was 15-50 eV with the angular range of the measurements being 10°-90°. All measured DCSs displayed forward-peaked angular distributions, consistent with the relatively large magnitudes for the dipole moment and dipole polarizability of pyrimidine. Excitations to triplet states were found to be particularly important in some energy loss features at the lower incident electron energies. To the best of our knowledge there are no other experimental data or theoretical computations against which we can compare the present results.

摘要

我们报告了嘧啶电子态的电子碰撞激发的微分截面(DCS)测量结果。本测量的能量范围为 15-50 eV,测量的角度范围为 10°-90°。所有测量的 DCS 都显示出前向峰角分布,这与嘧啶的偶极矩和偶极极化率的相对较大值一致。在较低入射电子能量的一些能量损失特征中,发现三重态的激发特别重要。据我们所知,目前还没有其他实验数据或理论计算可以与我们的结果进行比较。

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