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在厌氧-缺氧-好氧移动床生物反应器系统中对苯酚、硫氰酸盐和氨氮去除的动力学分析。

Kinetic analysis of phenol, thiocyanate and ammonia-nitrogen removals in an anaerobic-anoxic-aerobic moving bed bioreactor system.

机构信息

Centre for Environment, Indian Institute of Technology Guwahati, Assam 781039, India.

出版信息

J Hazard Mater. 2011 Jun 15;190(1-3):260-7. doi: 10.1016/j.jhazmat.2011.03.038. Epub 2011 Mar 21.

DOI:10.1016/j.jhazmat.2011.03.038
PMID:21497997
Abstract

A simulated wastewater containing phenol (2500 mg/L), thiocyanate and ammonia-nitrogen (500 mg/L) was treated in an anaerobic (R1)-anoxic (R2)-aerobic (R3) moving bed biofilm reactor system at different hydraulic retention time (HRT) intervals (total HRT 3-8 days, R1: 1.5-4 days; R2: 0.75-2 days and R3: 0.75-2 days) and feed thiocyanate (SCN(-)) concentrations (110-600 mg/L) to determine substrate removal kinetics. In R1, phenol and COD reduction and specific methanogenic activity were inhibited due to the increase of SCN(-) in feed. Bhatia et al. model having inbuilt provision of process inhibition described the kinetics of COD and phenol utilization with maximum utilization rates of 0.398 day(-1) and 0.486 day(-1), respectively. In R2 and R3 modified Stover-Kincannon model was suitable to describe substrate utilization. In R2 respective maximum SCN(-), phenol, COD and NO(3)(-)-N utilization rates were 0.23, 5.28, 37.7 and 11.82 g/L day, respectively. In aerobic reactor R3, COD, SCN(-) and NH(4)(+)-N removal rates were, respectively, 10.53, 1.89, and 2.17 g/L day. The minimum total HRT of three-stage system was recommended as 4 days.

摘要

采用厌氧(R1)-缺氧(R2)-好氧(R3)移动床生物膜反应器系统,在不同水力停留时间(HRT)(总 HRT 为 3-8 天,R1:1.5-4 天;R2:0.75-2 天和 R3:0.75-2 天)和不同进料硫氰酸盐(SCN(-))浓度(110-600 mg/L)下处理含苯酚(2500 mg/L)、硫氰酸盐和氨氮(500 mg/L)的模拟废水,以确定基质去除动力学。在 R1 中,由于进料中 SCN(-)的增加,苯酚和 COD 的还原以及特定产甲烷活性受到抑制。具有内置过程抑制功能的 Bhatia 模型描述了 COD 和苯酚利用的动力学,最大利用速率分别为 0.398 天(-1)和 0.486 天(-1)。在 R2 和 R3 中,改进的 Stover-Kincannon 模型适合描述基质的利用。在 R2 中,相应的最大 SCN(-)、苯酚、COD 和 NO(3)(-)-N 利用速率分别为 0.23、5.28、37.7 和 11.82 g/L 天。在好氧反应器 R3 中,COD、SCN(-)和 NH(4)(+)-N 的去除速率分别为 10.53、1.89 和 2.17 g/L 天。建议三阶段系统的最小总 HRT 为 4 天。

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