自由基碳炔基化和碳烯基化烯烃。
Free-radical carboalkynylation and carboalkenylation of olefins.
机构信息
University of Bordeaux, Institut des Sciences Moléculaires, Talence, France.
出版信息
Org Lett. 2011 May 20;13(10):2658-61. doi: 10.1021/ol2007633. Epub 2011 Apr 19.
PMID:21504207
Abstract
Free-radical three-component carboalkynylation and -alkenylation of olefins have been developed. These involve the addition, across the double bond of an unactivated olefin, of a radical species α- to an electron-withdrawing group and an alkenyl or alkynyl moiety, derived from the corresponding sulfones.
摘要
自由基三组分碳炔基化和烯烃加成反应已经被开发出来。这些反应涉及到在未活化烯烃的双键上，自由基物种α-加成到一个吸电子基团和一个烯基或炔基部分，这部分来源于相应的砜。
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