Yang Yanjun, Chen Meiguo, Sha Congwei
Guangdong Food and Drug Vocational College, Guangzhou 510520, China.
Zhongguo Zhong Yao Za Zhi. 2011 Jan;36(2):162-5.
To study the triterpenoids and triterpenoid saponins of Viscum liquidambaricolum further, chemical constituents were isolated from the title plant by various chromatographic methods such as silica gel and ODS medium pressure column chromatography, Sephadex LH-20 column chromatography, et al. Their structures were elucidated by physiochemical properties and spectral analysis. Eight triterpenoids and triterpenoid saponins were isolated and identified as myricadiol(1), maslinic acid(2), 2alpha, 3beta, 23-trihydroxyolean-12-en-28-oic acid(3), oleanolic acid 3-O-beta-D-glucuronopyranoside-6'-O-methyl ester(4), oleanolic acid 3-O-beta-D-glucuropyranoside(5), oleanolic acid 3-O-beta-D-glucopyranosyl-(1-->2)-alpha-L-arabinopyranoside (6), 3-O-beta-D-glucuronopyranosyl-oleanolic acid-28-O-beta-D-glucopyranoside (7), 3-O-beta-D-glucuronopyranosyl-oleanolic acid-28-O-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside (8). Compounds 1-8 were isolated from this plant and the genus for the first time.
为进一步研究枫香槲寄生的三萜类及三萜皂苷类成分,采用硅胶柱色谱、ODS中压柱色谱、Sephadex LH-20柱色谱等多种色谱方法从该植物中分离化学成分。通过理化性质和光谱分析对其结构进行鉴定。分离并鉴定出8个三萜类及三萜皂苷类化合物,分别为杨梅二醇(1)、山楂酸(2)、2α,3β,23-三羟基齐墩果-12-烯-28-酸(3)、齐墩果酸3-O-β-D-葡萄糖醛酸吡喃糖苷-6'-O-甲酯(4)、齐墩果酸3-O-β-D-葡萄糖醛酸吡喃糖苷(5)、齐墩果酸3-O-β-D-葡萄糖吡喃糖基-(1→2)-α-L-阿拉伯吡喃糖苷(6)、3-O-β-D-葡萄糖醛酸吡喃糖基-齐墩果酸-28-O-β-D-葡萄糖吡喃糖苷(7)、3-O-β-D-葡萄糖醛酸吡喃糖基-齐墩果酸-28-O-β-D-葡萄糖吡喃糖基-(1→6)-β-D-葡萄糖吡喃糖苷(8)。化合物1-8均为首次从该植物及该属植物中分离得到。