在辛基取代的次氢茚骨架中引入空气和水分稳定的 p-单硫代苯醌。
Air- and moisture-stable p-monothiobenzoquinones incorporated in an octaalkyl-s-hydrindacene skeleton.
机构信息
Functional Elemento-Organic Chemistry Unit and Advanced Technology Support Division, RIKEN Advanced Science Institute, Wako, Saitama, Japan.
出版信息
Org Lett. 2011 May 20;13(10):2666-9. doi: 10.1021/ol200768b. Epub 2011 Apr 21.
PMID:21510697
Abstract
p-Monothiobenzoquinones incorporated in a fused-ring octaalkyl-s-hydrindacene skeleton have been synthesized as air- and moisture-stable reddish orange crystals by the oxidation of mercaptophenol derivatives with DDQ, which have been characterized by X-ray crystallography to show a planar quinoid framework.
摘要
p-单硫代苯醌与稠合环辛烷基-s-氢茚并骨架结合，通过用 DDQ 氧化巯基苯酚衍生物合成，得到了空气和水分稳定的红橙色晶体。这些化合物已经通过 X 射线晶体学进行了表征，显示出平面醌骨架。
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