Haque Rosenani A, Salman Abbas Washeel, Hemamalini Madhukar, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 5;67(Pt 3):o562-3. doi: 10.1107/S1600536811003916.
In the title molecular salt, C(25)H(38)N(4) (2+)·2PF(6) (-), one of the butyl groups and four F atoms in the basal plane of one of the PF(6) (-) octa-hedra are disordered over two sets of sites, with occupancy ratios of 0.704 (5):0.296 (5) and 0.71 (3):0.29 (3), respectively. The central benzene ring makes dihedral angles of 85.17 (12) and 81.97 (12)° with the terminal imidazole rings. In the crystal, cations and anions are linked together via inter-molecular C-H⋯F hydrogen bonds forming a three-dimensional network.
在标题分子盐C(25)H(38)N(4)(2+)·2PF(6)(-)中，其中一个PF(6)(-)八面体底面的一个丁基和四个氟原子在两组位置上无序排列，占有率分别为0.704 (5):0.296 (5)和0.71 (3):0.29 (3)。中心苯环与末端咪唑环的二面角分别为85.17 (12)°和81.97 (12)°。在晶体中，阳离子和阴离子通过分子间C-H⋯F氢键连接在一起，形成三维网络。
