2,4-双[(3-烯丙基-咪唑鎓-1-基)甲基]均三甲苯双(六氟磷酸盐)
2,4-Bis[(3-allyl-imidazolium-1-yl)meth-yl]mesitylene bis-(hexa-fluoridophosphate).
作者信息
Haque Rosenani A, Ghdhayeb Mohammed Z, Hemamalini Madhukar, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2068. doi: 10.1107/S1600536811027541. Epub 2011 Jul 16.
Abstract
In the title mol-ecular salt, C(23)H(30)N(4) (2+)·2PF(6) (-), the central benzene ring of the cation makes dihedral angles of 89.80 (8) and 85.23 (7)° with the pendant imidazole rings. In the crystal, the cations and anions are linked by numerous C-H⋯F hydrogen bonds, thereby forming a three-dimensional network.
摘要
在标题分子盐C(23)H(30)N(4)(2+)·2PF(6)(-)中，阳离子的中心苯环与悬垂的咪唑环形成的二面角分别为89.80 (8)°和85.23 (7)°。在晶体中，阳离子和阴离子通过大量的C—H⋯F氢键相连，从而形成三维网络。
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