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二氯双（1,10-菲啰啉）锌（II）四氯（1,10-菲啰啉）铋（III）一水合物

Chloridobis(1,10-phenanthroline)zinc(II) tetra-chlorido(1,10-phenan-throline)bis-muthate(III) monohydrate.

作者信息

Song Chunlei, Chai Wenxiang, Song Li, Yang Yunyun, Lin Jian

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m109-10. doi: 10.1107/S1600536810052682.

DOI:10.1107/S1600536810052682
PMID:21522522
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3050139/
Abstract

In the crystal structure of the title monohydrate salt, [ZnCl(C(12)H(8)N(2))(2)][BiCl(4)(C(12)H(8)N(2))]·H(2)O, the ionic components are linked into three-dimensional supra-molecular channels by five pairs of C-H⋯Cl hydrogen bonds and π-π stacking inter-actions with an inter-planar distance of 3.643 (2) Å. The solvent water mol-ecules are lodged in the channels.

摘要

在标题一水合盐[ZnCl(C₁₂H₈N₂)₂][BiCl₄(C₁₂H₈N₂)]·H₂O的晶体结构中，离子组分通过五对C—H⋯Cl氢键和平面间距离为3.643 (2) Å的π-π堆积相互作用连接成三维超分子通道。溶剂水分子位于通道中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/206b/3050139/8cb2e4c66986/e-67-0m109-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/206b/3050139/d1e9bea3e269/e-67-0m109-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/206b/3050139/8cb2e4c66986/e-67-0m109-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/206b/3050139/d1e9bea3e269/e-67-0m109-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/206b/3050139/8cb2e4c66986/e-67-0m109-fig2.jpg

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