硝酸一水合（碳酸根 - κO,O'）双 -（1,10 - 菲咯啉 - κN,N'）钴（III）
(Carbonato-κO,O')bis-(1,10-phenan-throline-κN,N')cobalt(III) nitrate monohydrate.
作者信息
Andaç Omer, Yolcu Zuhal, Büyükgüngör Orhan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m46-7. doi: 10.1107/S1600536809052763.
The crystal structure of the title compound, [Co(CO(3))(C(12)H(8)N(2))(2)]NO(3)·H(2)O, consists of Co(III) complex cations, nitrate anions and uncoordinated water mol-ecules. The Co(III) cation is chelated by a carbonate anion and two phenanthroline ligands in a distorted octa-hedral coordination geometry. A three-dimensional supra-molecular structure is formed by O-H⋯O and C-H⋯O hydrogen bonding, C-H⋯π and aromatic π-π stacking [centroid-centroid distance = 3.995 (1)Å] inter-actions.
标题化合物[Co(CO₃)(C₁₂H₈N₂)₂]NO₃·H₂O的晶体结构由Co(III)配合物阳离子、硝酸根阴离子和未配位的水分子组成。Co(III)阳离子通过一个碳酸根阴离子和两个菲咯啉配体以扭曲的八面体配位几何构型螯合。通过O-H⋯O和C-H⋯O氢键、C-H⋯π和芳香π-π堆积作用[质心-质心距离 = 3.995 (1)Å]形成三维超分子结构。
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