Dicarbonyl-chlorido(phen-oxy-thio-carbonyl-κC,S)bis-(triphenyl-phosphane-κP)molybdenum(II).
作者信息
Lee Gene-Hsiang, Wang Hsiao-Fen, Yih Kuang-Hway, Huang Shou-Ling
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m117-8. doi: 10.1107/S1600536810052530.
Abstract
In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa-hedron. The phen-oxy-thio-carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π-π inter-molecular inter-actions and a supra-molecular aggregation is determined by inter-molecular C-H⋯O, C-H⋯Cl, C-H⋯π(arene) hydrogen bonds and CO⋯π(arene) inter-actions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å].
摘要
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