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Dicarbonyl-chlorido(phen-oxy-thio-carbonyl-κC,S)bis-(triphenyl-phosphane-κP)molybdenum(II).

作者信息

Lee Gene-Hsiang, Wang Hsiao-Fen, Yih Kuang-Hway, Huang Shou-Ling

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m117-8. doi: 10.1107/S1600536810052530.

Abstract

In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa-hedron. The phen-oxy-thio-carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π-π inter-molecular inter-actions and a supra-molecular aggregation is determined by inter-molecular C-H⋯O, C-H⋯Cl, C-H⋯π(arene) hydrogen bonds and CO⋯π(arene) inter-actions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15ac/3050204/7ca2854c08e7/e-67-0m117-fig1.jpg

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