Nimthong-Roldán Arunpatcha, Promsuwhan Nichakan, Puetpaiboon Walailak, Wattanakanjana Yupa
Department of Chemistry, Boston University, Boston, Massachusetts 02215, USA.
Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.
Acta Crystallogr E Crystallogr Commun. 2017 Jan 1;73(Pt 1):41-44. doi: 10.1107/S2056989016019368.
The mononuclear mixed-ligand title complex, [CuCl(CHNOS)(CHP)], displays a distorted tetra-hedral coordination sphere around the Cu atom, with two P atoms from two tri-phenyl-phosphane mol-ecules, one terminal S atom from a 1-(4-nitro-phen-yl)thio-urea mol-ecule and a chloride ion as ligands. An intra-molecular N-H⋯Cl hydrogen bond stabilizes the mol-ecular conformation [graph-set motif (6)]. In the crystal, further N-H⋯Cl hydrogen bonds connect individual mol-ecules into zigzag chains parallel to [001]. The chains are linked by weak C-H⋯O hydrogen-bonding inter-actions into a three-dimensional network.
单核混合配体标题配合物[CuCl(CHNOS)(CHP)]在铜原子周围呈现出扭曲的四面体配位环境，其中两个三苯基膦分子的两个磷原子、一个1-(4-硝基苯基)硫脲分子的一个端基硫原子和一个氯离子作为配体。分子内的N-H⋯Cl氢键稳定了分子构象[图式(6)]。在晶体中，进一步的N-H⋯Cl氢键将单个分子连接成平行于[001]的锯齿链。这些链通过弱的C-H⋯O氢键相互作用连接成三维网络。
Zotero 插件
