{1,1'-[丁烷-1,4-二基双(腈基亚甲基)]二-2-萘酚根合}铜(II)乙醇单溶剂合物
{1,1'-[Butane-1,4-diylbis(nitrilo-methyl-idyne)]di-2-naphtho-lato}copper(II) ethanol monosolvate.
作者信息
Kargar Hadi, Kia Reza
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 24;67(Pt 1):m128. doi: 10.1107/S1600536810053183.
The asymmetric unit of the title compound, [Cu(C(26)H(22)N(2)O(2))]·C(2)H(5)OH, comprises a Schiff base complex and an ethanol mol-ecule of crystallization. The Cu(II) atom shows a distorted square-planar geometry. The dihedral angle between the two aromatic rings is 48.16 (13)°. The crystal structure is stabilized by inter-molecular O-H⋯O and C-H⋯O hydrogen bonds and inter-molecular π-π inter-actions with centroid-centroid distances in the range 3.485 (2)-3.845 (3) Å.
标题化合物[Cu(C₂₆H₂₂N₂O₂)]·C₂H₅OH的不对称单元包含一个席夫碱配合物和一个结晶乙醇分子。Cu(II)原子呈现出扭曲的平面正方形几何构型。两个芳香环之间的二面角为48.16 (13)°。晶体结构通过分子间的O-H⋯O和C-H⋯O氢键以及分子间的π-π相互作用得以稳定，其质心间距在3.485 (2)-3.845 (3) Å范围内。
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