{6,6'-二甲氧基-2,2'-[4,5-二甲基-邻亚苯基双(次氮基甲基亚基)]二酚根合}镍(II)
{6,6'-Dimeth-oxy-2,2'-[4,5-dimethyl-o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}nickel(II).
作者信息
Kargar Hadi, Kia Reza, Tahir Muhammad Nawaz, Sahraei Atefeh
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1246. doi: 10.1107/S1600536810035890.
Abstract
In the title Schiff base complex, [Ni(C(24)H(22)N(2)O(4))], the Ni(II) atom has a slightly distorted square-planar coordination environment. The dihedral angles between the central benzene ring and the two outer rings are 7.62 (16) and 9.78 (17)°. The crystal structure is stabilized by inter-molecular C-H⋯O hydrogen bonds and π-π inter-actions with a centroid-centroid distance of 3.8218 (19) Å.
摘要
在席夫碱配合物[Ni(C₂₄H₂₂N₂O₄)]的标题中，Ni(II)原子具有略微扭曲的平面正方形配位环境。中心苯环与两个外环之间的二面角分别为7.62 (16)°和9.78 (17)°。晶体结构通过分子间C—H⋯O氢键和质心间距为3.8218 (19) Å的π-π相互作用得以稳定。
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