（5,7,7,12,14,14 - 六甲基 - 1,4,8,11 - 四氮杂环十四碳 - 4,11 - 二烯）镍（II）双 - [O,O'-双 -（4 - 叔丁基苯基）二硫代磷酸酯]
(5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-4,11-diene)nickel(II) bis-[O,O'-bis-(4-tert-butyl-phen-yl) dithio-phosphate].
作者信息
Lai Chuan, Xie Bin, Zou Li-Ke, Feng Jian-Shen
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m17. doi: 10.1107/S1600536810049615.
The title salt, Ni(C(16)H(32)N(4))(2), comprises a centrosymmetric Ni(Me(6)[14]dieneN(4)) dication (Me(6)[14]dieneN(4) is 5,7,7,12,14,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-4,11-diene) and two O,O'-bis-(4-tert-butyl-phen-yl) dithio-phosphate anions. The Ni(II) ion lies on an inversion centre and displays a slightly distorted NiN(4) square-planar chelation arrangement with four N atoms from the Me(6)[14]dieneN(4) macrocycle. Two S atoms from symmetry-related anions are located in pseudo-axial positions with respect to the Ni(II) ion, with Ni⋯S distances of 3.2991 (7) Å. Inter-molecular N-H⋯S and C-H⋯S hydrogen bonds link the complex cation and pair of anions into a 1:2 type salt.
标题盐Ni(C(16)H(32)N(4))(2)由一个中心对称的Ni(Me(6)[14]二烯N(4))二价阳离子（Me(6)[14]二烯N(4)为5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四碳-4,11-二烯）和两个O,O'-双-(4-叔丁基苯基)二硫代磷酸根阴离子组成。Ni(II)离子位于一个反演中心，与来自Me(6)[14]二烯N(4)大环的四个N原子形成略微扭曲的NiN(4)平面正方形螯合结构。来自对称相关阴离子的两个S原子相对于Ni(II)离子位于假轴向位置，Ni⋯S距离为3.2991 (7) Å。分子间的N-H⋯S和C-H⋯S氢键将络合阳离子和一对阴离子连接成1:2型盐。
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